Toilet paper can spread PFAS into wastewater

Toilet paper from around the world contains low levels of PFAS, likely contributing these "forever chemicals" to wastewater.

Toilet paper from around the world contains low levels of PFAS, likely contributing these “forever chemicals” to wastewater.

Wastewater can provide clues about a community’s infectious disease status, prescription medication, and illicit drug use. But looking at sewage also provides information on persistent and potentially harmful compounds, such as per- and polyfluoroalkyl substances (PFAS), that get released into the environment.

Now, researchers publishing in Environmental Science & Technology Letters report an unexpected source of these substances in wastewater systems—toilet paper.

PFAS have been detected in many personal care products, such as cosmetics and cleansers, that people use daily and then wash down the drain. But not many researchers have considered whether toilet paper, which also ends up in wastewater, could be a source of the chemicals.

Some paper manufacturers add PFAS when converting wood into pulp. PFAS can get left behind and contaminate the final paper product. In addition, recycled toilet paper could be made with fibres from materials containing PFAS. So, Timothy Townsend and colleagues from the University of Florida wanted to assess this potential input to wastewater systems and test toilet paper and sewage for these compounds.

The researchers gathered toilet paper rolls sold in North, South and Central America; Africa; and Western Europe. They collected sewage sludge samples from U.S. wastewater treatment plants. Then they extracted PFAS from the paper and sludge solids and analysed them for 34 compounds.

The primary PFAS detected were disubstituted polyfluoroalkyl phosphates (diPAPs). These compounds can convert to more stable PFAS, such as perfluorooctanoic acid, which is potentially carcinogenic. Specifically, 6:2 diPAP was the most abundant in both samples but was in the parts-per-billion range.

Then, the team combined their results with data from other studies. That included measurements of PFAS levels in sewage and per capita toilet paper use in various countries. They calculated that it contributed about four per cent of the 6:2 diPAP in sewage in the U.S. and Canada, 35 per cent in Sweden and up to 89 per cent in France.

The researchers found that North Americans use more toilet paper than people living in many other countries. However, the calculated percentages suggest that most PFAS enter the U.S. wastewater systems from cosmetics, textiles, food packaging or other sources, the researchers say. They added that this study identifies toilet paper as a source of PFAS in wastewater treatment systems. In some places, it can be a significant source.

Related Articles:

Send this to a friend