A new sensor for detecting “forever chemicals” in drinking water

Converting PFAS and forever chemicals into a valuable resource

The technology could offer a cheap, fast way to test for PFAS and other forever chemicals. These have been linked to cancer and other health problems.

MIT chemists have designed a sensor that detects tiny quantities of perfluoroalkyl and polyfluoroalkyl substances (PFAS) — chemicals found in food packaging, nonstick cookware, and many other consumer products.

These compounds, also known as “forever chemicals” because they do not break down naturally, have been linked to a variety of harmful health effects, including cancer, reproductive problems, and disruption of the immune and endocrine systems.

Using the new sensor technology, the researchers showed they could detect PFAS levels as low as 200 parts per trillion in a water sample. The device they designed could offer a way for consumers to test their drinking water, and it could also be useful in industries that rely heavily on PFAS chemicals, including the manufacture of semiconductors and firefighting equipment.

“There’s a real need for these sensing technologies. We’re stuck with these chemicals for a long time, so we need to be able to detect them and get rid of them,” says Timothy Swager, the John D. MacArthur Professor of Chemistry at MIT and the senior author of the study, which appears this week in the Proceedings of the National Academy of Sciences.

The paper’s other authors are Sohyun Park, a former MIT postdoc and lead author, and Collette Gordon, an MIT graduate student.

Detecting PFAS and forever chemicals

Coatings containing PFAS chemicals are used in thousands of consumer products. In addition to nonstick coatings for cookware, they are commonly used in water-repellent clothing, stain-resistant fabrics, grease-resistant pizza boxes, cosmetics, and firefighting foams.

These fluorinated chemicals, widely used since the 1950s, can be released into water, air, and soil from factories, sewage treatment plants, and landfills. They have been found in drinking water sources in all 50 states.

In 2023, the Environmental Protection Agency created an “advisory health limit” for two of the most hazardous PFAS chemicals: perfluorooctanoic acid (PFOA) and perfluorooctyl sulfonate (PFOS). These advisories call for a limit of 0.004 parts per trillion for PFOA and 0.02 parts per trillion for PFOS in drinking water.

Currently, consumers can only determine if their drinking water contains PFAS by sending a water sample to a laboratory that performs mass spectrometry testing. However, this process takes several weeks and costs hundreds of dollars.

The MIT team designed a sensor based on lateral flow technology to create a cheaper and faster way to test for PFAS — the same approach used for rapid COVID-19 and pregnancy tests. Instead of a test strip coated with antibodies, the new sensor is embedded with a special polymer known as polyaniline, which can switch between semiconducting and conducting states when protons are added to the material.

The researchers deposited these polymers onto a strip of nitrocellulose paper. They coated them with a surfactant that can pull fluorocarbons such as PFAS out of a drop of water on the strip. When this happens, protons from the PFAS are drawn into the polyaniline and turn it into a conductor, reducing the material’s electrical resistance. This change in resistance, which can be measured precisely using electrodes and sent to an external device such as a smartphone, quantifies how much PFAS is present.

This approach works only with PFAS that are acidic, which includes two of the most harmful PFAS — PFOA and perfluorobutanoic acid (PFBA).

A user-friendly system

The current version of the sensor can detect concentrations as low as 200 parts per trillion for PFBA and 400 parts per trillion for PFOA. This is not quite low enough to meet the current EPA guidelines, but the sensor uses only a fraction of a millilitre of water. The researchers are now working on a larger-scale device that could filter about a litre of water through a membrane made of polyaniline, and they believe this approach should increase the sensitivity by more than a hundredfold to meet the very low EPA advisory levels.

“We do envision a user-friendly, household system,” Swager says. “You can imagine putting in a litre of water, letting it go through the membrane, and having a device that measures the change in membrane resistance.”

Such a device could offer a cheaper, rapid alternative to current PFAS detection methods. If PFAS are detected in drinking water, commercially available filters can be used on household drinking water to reduce those levels. The new testing approach could also be useful for factories that manufacture products with PFAS chemicals, so they could test whether the water used in their manufacturing process is safe to release into the environment.

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